- Program Areas
- Installation Energy and Water
- Environmental Restoration
- Munitions Response
- Resource Conservation and Resiliency
- Weapons Systems and Platforms
Investigating Electrochemical and Reductive Approaches for Treatment of Perfluoroalkyl Substances in Groundwater
Dr. Charles Schaefer | CDM Smith
The objective of this project is to develop and assess the use of electrocatalytic and catalytic approaches for in situ treatment of poly- and perfluoroalkyl substances (PFAS) in groundwater. Specifically, electrocatalytic approaches will focus on the ability of ruthenium oxide-coated titanium (Ti/RuO2) and other mixed metal oxide (MMO) anodes to oxidize PFAS in groundwater under a wide range of conditions; catalytic approaches will focus on the use of supported rhodium-based catalysts for the hydrodefluorination of PFAS in groundwater under ambient conditions. Preliminary bench-scale testing of these technologies by the project team, along with previously published studies, indicate that these technologies hold exceptional promise for the in situ treatment of PFAS under ambient conditions at many Department of Defense (DoD) facilities. Reaction kinetics, reaction intermediates and products, optimal catalyst materials, geochemical and co-occurring chemical impacts on treatment effectiveness, and potential applicability to field-scale remediation will be evaluated as part of this project.
This project will consist of a series of bench-scale batch and column experiments using both MMO anodes and supported rhodium-based catalysts. Initial efforts will focus on selecting and/or formulating optimal MMO and rhodium-based catalyst materials for treatment of PFAS. Batch experiments, using simplified aqueous systems (with respect to water geochemistry and contaminant mixtures), will then be performed to obtain a fundamental understanding of reaction mechanisms, pathways, and rates. To understand the potential formation of harmful degradation products, substantial analytical effort will be expended to provide adequate characterization of transformation products. Subsequent batch experiments using synthetic and natural groundwaters will employ the use of PFAS mixtures (including precursor compounds), hydrocarbon or chlorinated solvent co-occurring chemicals, and a range of geochemical conditions. Column experiments will be performed for both the electrocatalytic and catalyst systems to evaluate material longevity and to assess remedial performance under conditions more representative of potential field-scale implementation. Detailed analyses will be performed on the electrode and catalyst materials to assess the nature and extent of any fouling or deactivation mechanisms.
PFAS have become a concern of growing urgency for DoD. With several studies showing the presence, or potential presence, of these compounds in groundwater associated with fire training areas, adverse PFAS impacts on groundwater are potentially widespread at DoD facilities. However, with conventional technologies ineffective or inefficient for treatment and the well-documented recalcitrance of PFAS with respect to natural or enhanced degradation processes, cost-effective in situ treatment options for these compounds are currently not available. Development of electrocatalytic and catalytic approaches is expected to provide remedial tools that can be efficiently and cost-effectively applied for treatment of PFAS-impacted groundwater at a wide range of DoD facilities. (Anticipated Project Completion - 2018)
Liu, J., D.J. Van Hoomissen, T. Liu, A. Maizel, X. Huo, S.R. Fernández, C. Ren, X. Xiao, Y. Fang, C. Schaefer, C.P. Higgins, S. Vyas, and T.J. Strathmann. 2018. Reductive Defluorination of Branched Per-and Polyfluoroalkyl Substances with Cobalt Complex Catalysts. Environmental Science & Technology Letters. doi:10.1021/acs.estlett.8b00122
Schaefer, C.E., C. Andaya, A. Burant, C.W. Condee, A. Urtiaga, T.J. Strathmann, and C.P. Higgins. 2017. Electrochemical Treatment of Perfluorooctanoic Acid and Perfluorooctane Sulfonate: Insights into Mechanisms and Application to Groundwater Treatment. Chemical Engineering Journal, 317:424-432.
Schaefer, C.E., S. Choyke, P.L. Ferguson, C. Andaya, A. Burant, A. Maizel, T.J. Strathmann, and C.P. Higgins. 2018. Electrochemical Transformations of Perfluoroalkyl Acid (PFAA) Precursors and PFAAs in Groundwater Impacted with Aqueous Film Forming Foams. Environmental Science & Technology, 52(18):10689-10697.
Schaefer, C.E., C. Andaya, A. Maizel, and C.P. Higgins. 2019. Assessing Continued Electrochemical Treatment of Groundwater Impacted by Aqueous Film-Forming Foams. Journal of Environmental Engineering, 145(12):06019007.